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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 5, 1975 - Issue 5
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Original Articles

Selective Cleavage of β-Keto and Vinylogous β-Keto Esters by 3-Quinuclidinol

Edward J. Parish Department of Chemistry, Mississippi State University, Mississippi, Mississippi, 39762
,
Bao-Shan Huang Department of Chemistry, Mississippi State University, Mississippi, Mississippi, 39762
&
D. Howard Miles Department of Chemistry, Mississippi State University, Mississippi, Mississippi, 39762
Pages 341-345 | Received 15 Apr 1975, Published online: 06 Dec 2006
 
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Abstract

As a result of a continuing study utilizing nitrogenous bases2–6, we now wish to report that the base 3-quinuclidinol (13) is useful for the cleavage of β-keto and vinylogous β-keto esters.

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