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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 6, 1976 - Issue 8
72
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Original Articles

A Convenient Tertiary Amine Synthesis. Use of Methylenedimethylammonium Trifluoroacetate

Pages 539-542 | Received 02 Aug 1976, Published online: 05 Dec 2006
 

Abstract

Methylenedimethylammonium trifluoroacetate and related Mannich reagents have received rather little attention in view of the novel applications conceptually possible for these salts.1 Specifically, these reagents offer two potential advantages to the usual approach, enhanced reactivity and employment of aprotic conditions. We wished to explore the latter concept by coupling the title reagent with various organometallic reagents.

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