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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 6, 1976 - Issue 7
69
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Original Articles

The Addition of Arenesulfinyl Chlorides to Olefins

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Pages 495-501 | Received 07 Jul 1976, Published online: 01 Feb 2007
 

Abstract

It has long been known that arenesulfenyl halides will add to olefins to yield β-halosulfides1. Arene-sulfonyl halides have been shown to react with alkenes2 polyenes3, alkynes4 and allenes5. Although sulfinyl halides have been synthesized for some time6 there appears to be but one brief mention of their reaction with olefins7. In view of the recent increased interest in sulfoxides we decided to reinvestigate this reaction.

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