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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 7, 1977 - Issue 2
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Original Articles

The Synthesis of Anthracenes from Anthraquinones

Pages 161-166 | Received 19 Jan 1977, Published online: 23 Oct 2006
 

Abstract

The preparation of a series of halogen-substituted anthracenes and anthroic acids was of interest in connection with work in another area.1 The classical zinc-ammonia procedure2 for the reduction of anthraquinones to anthracenes was satisfactory for a number of these compounds, but an unacceptable yield of very difficult-to-purify product mixture from 6,7-dichloroanthraquinone-1-carboxylic acid induced a search for a more efficient conversion. A further concern was the possibility of halogen expulsion under these conditions as noted much earlier by Fischer and Sapper3 for 4-chloronthraquionone-1-carboxylic acid and by Kircher4 for 1,2,3,4-tetrachloroanthraquionone.

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