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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 7, 1977 - Issue 3
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Original Articles

The γ-Methoxycrotonate Anion: Another Bifunctional Enolate

Pages 189-193 | Received 14 Feb 1977, Published online: 23 Oct 2006
 

Abstract

We reported that γ-methylthiocrotonate ester anion is a versatile bifunctional enolate1; however, the hydrolysis of the methylthioenol products was difficult. To circumvent this problem and to demonstrate an extended versatility of this enolate system, the chemistry of the γ-methoxycrotonate ester anion was studied.

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