Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 7, 1977 - Issue 6
390
Views
65
CrossRef citations to date
0
Altmetric
Original Articles

4-Formyl-2-cyclohexenone Derivatives

&
Pages 409-415 | Received 06 Jun 1977, Published online: 23 Oct 2006
 

Abstract

Recent interest in γ-alkylation of α,β-unsaturated carbonyl compounds1 has focused on the possibility of α'-alkylation of β-alkoxy α,β-unsaturated keto systems,2 e.g. 1, hydride reduction of the products and acid-catalyzed hydrolysis of the resultant alkoxyallyl alcohols.3 Quite some time earlier the α' carbon had been shown to be the site of acylation of a β-alkoxy α,β-unsaturated ketone, i.e. 12 on formylation.4 Since a reduction-hydrolysis reaction sequence on the O-protected derivative 3 4b might lead to 4-formyl-2-cyclohexenone (or its equivalent), a trifunctional substance of potential interest in organic synthesis, some of the chemistry of ketones 2 and 3 was investigated.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.