Addition of Organocuprates to Cyclobutenyl Esters. Synthesis of (±)-Grandisol: Synthetic Communications: Vol 9, No 4

Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 9, 1979 - Issue 4

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Abstract

The conjugate addition of organocuprates to certain esters², methylene lactones³, and enol lactones⁴ has been demonstrated. We report herein that cyclobutenyl esters readily undergo conjugate addition with these reagents, and that this reaction has been used to synthesize the boll weevil pheromone (±)-grandisol (18).⁵

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Addition of Organocuprates to Cyclobutenyl Esters. Synthesis of (±)-Grandisol

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Addition of Organocuprates to Cyclobutenyl Esters. Synthesis of (±)-Grandisol

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