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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 9, 1979 - Issue 8
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Original Articles

A Preparative Synthesis of D,L-Gabaculine

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Pages 741-750 | Received 17 May 1979, Published online: 05 Dec 2006
 

Abstract

The γ-aminobutyric acid-α-ketoglutaric acid transaminase inhibitor, gabaculine (1) was first isolated as an optically active amorphous powder from a culture filtrate of streptomyces toyacaenis subspecies 1039 by Mishima and co-workers in 19761. The structure (1) was assigned on the basis of physical and chemical data and has been confirmed by two total syntheses of the racemic compound1,2.

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