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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 9, 1979 - Issue 3
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Original Articles

Stereoselectivity in the Catalytic Hydrogenation of an Enamine. Selective Formation of Either CIS- or trans- Tertiary Amines

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Pages 223-231 | Received 28 Sep 1978, Published online: 05 Dec 2006
 

Abstract

Conditions have been found where catalytic hydrogenation of the enamine (II) may produce either the trans-2- (3,4-dichlorophenyl) -3 -NN-dimethylaminomethylbicyclo[2,2,2]octane exclusively, or the cis-isomer with high stereoselectivity.

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