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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 10, 1980 - Issue 2
46
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Original Articles

Regiospecific Synthesis of α-Alkylated Ketones

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Pages 139-145 | Received 31 Aug 1979, Published online: 05 Dec 2006
 

Abstract

Several solutions have been developed to avoid the troublesome di- and polyalkylation encountered in ketone enolate alkylations1, including use of the covalent Li enolate, or “additives” to tighten the metal-oxygen bond (M = Si2,3,4, Sn5,6, Al6, B7,8,9).

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