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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 11, 1981 - Issue 10
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Original Articles

Crown Ether Catalysis in the Synthesis of Xanthates

Robert Chěnevert Département de Chimie, Faculté des Sciences et de Génie, Université Laval, Québec, Canada, G1K 7P4
,
Robert Paquin Département de Chimie, Faculté des Sciences et de Génie, Université Laval, Québec, Canada, G1K 7P4
&
André Rodrigue Département de Chimie, Faculté des Sciences et de Génie, Université Laval, Québec, Canada, G1K 7P4
Pages 817-821 | Published online: 05 Dec 2006
 
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Abstract

Xanthates (0,S-dialkyl dithiocarbonates) received much attention in connection with technological1 and synthetic applications2. Pyrolytic elimination of xanthates, called the Chugaev reaction, has been widely used as a method of dehydrating alcohols without rearrangement of carbon skeleton3.

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