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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 12, 1982 - Issue 2
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Original Articles

Electrogenerated Bases IV1. Reaction of Electrogenerated Superoxide With Some Carbon Acids

Pauline M. Allen Department of Chemistry, University of California, Los Angeles, California, 90024
,
Ulrich Hess Department of Chemistry, University of California, Los Angeles, California, 90024
,
Christopher S. Foote Department of Chemistry, University of California, Los Angeles, California, 90024
&
Manuel M. Baizer School of Engineering and Applied Science, University of California, Los Angeles, California, 90024
Pages 123-129 | Published online: 05 Dec 2006
 
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Abstract

Superoxideion (O2†)is formed electrochemically by one-electron reduction of o2 in aprotic media. Since o2 7 is an anion radical, it could, at least in principle, function as (a) an electron transfer (reducing) agent, (b) a base, (o) a hydrogen atom abstractor (most) easily as its conjugate acid HO2), and (d) a nucleophile.

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