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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 12, 1982 - Issue 14
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Original Articles

Zinc (0)-Mediated Formation of Carbon-Carbon Bond from γ-Bromo Crotonate

, &
Pages 1147-1154 | Published online: 05 Dec 2006
 

Abstract

The coupling reaction of allylic halides with diffferent organometallic reagents has been widely utilized for synthetic purpose.1 Unfortunately, with the exception of primary halides which give mostly α attack and of hindered substrates which prefer γ attack, the lack of regioselectivity is a great handicap for the generalization of the method.

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