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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 5
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Original Articles

Crown Ether Catalysis in the Synthesis of Cyanohydrin Derivatives

Robert Chěnevert Département de chimie, Faculté des sciences et de génie, Université Laval, Québec, Canada, G1K 7P4
,
Raymond Plante Département de chimie, Faculté des sciences et de génie, Université Laval, Québec, Canada, G1K 7P4
&
Normand Voyer Département de chimie, Faculté des sciences et de génie, Université Laval, Québec, Canada, G1K 7P4
Pages 403-409 | Published online: 06 Dec 2006
 
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Abstract

Carbonyl compounds react with cyanide ion under phase transfer catalysis (18-crown-6) to give cyanohydrin anions which are trapped by acid chlorides, anhydrides or alkylating agents to give cyanohydrin derivatives.

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