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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 11
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Original Articles

Unambiguous Mono Deuterium Labelling of Alkyl Ethyl Ketones at the α Position of the Ethyl Group by Ruthenium (III) Catalyzed Isomerization of O-Deuterated Allylic Alcohols

C. Georgoulis Laboratoire de Cinétique et Mécanismes de Réactions Organiques, C.N.R.S. ER 84. Université Pierre et Marie Curie, 4 Place Jussieu, 75230, PARIS CEDEX 05, FRANCE
,
J. M. Valéry Laboratoire de Cinétique et Mécanismes de Réactions Organiques, C.N.R.S. ER 84. Université Pierre et Marie Curie, 4 Place Jussieu, 75230, PARIS CEDEX 05, FRANCE
&
G. Ville Laboratoire de Cinétique et Mécanismes de Réactions Organiques, C.N.R.S. ER 84. Université Pierre et Marie Curie, 4 Place Jussieu, 75230, PARIS CEDEX 05, FRANCE
Pages 1043-1046 | Published online: 06 Dec 2006
 
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Abstract

Ruthenium (III) tris acetylacetonate is an efficient catalyst for the isomerization of O-deuterated alkylvinyl carbinols allowing thus a facile route to the title compounds.

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