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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 12
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Original Articles

A Biphasic Process for the Oxidation of Sulfides: A New Convenient Route to Sulfoxides

F. Gasparrini Istituto di Chiraica Orgánica, Via del Castro Laurenziano 9, 00161, Roma, Italy
,
M. Giovannoli Istituto di Chiraica Orgánica, Via del Castro Laurenziano 9, 00161, Roma, Italy
,
L. Maresca Istituto di Chimica Generale ed Irorganica, Università di Venezia, Italy
,
G. Natile Dipartimento Farmaco-Chimico, Università di Bari, Italy
&
G. Palmieri Dipartimento di Scienze Chimiche, Università di Camerino, Italy
Pages 1111-1117 | Published online: 06 Dec 2006
 
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Abstract

A biphasic (nitromethane/water) process is provided for the oxidation of alkyl- and ary l-sulf ides by aqueous nitric and sulfuric acids (20% each). This represents a preparatively useful and convenient route to sulfoxides.

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