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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 12
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Original Articles

Diterpene Total Synthesis : An Improved Stereoselective Route to (±)-3,4,5,5a,7,8,8aα,8bα-Octahydro-2aα,5aβ-Dimethyl-2H-Naphto-|1,8-Bc|Furan-2,6-(2aH)-Dione

Luc Van Hijfte Department of Organic Chemistry, State University of Ghent, Laboratory for Organic Synthesis, Krijgslaan, 281 (S. 4), B-9000, GENT, Belgium
&
Maurits Vandewalle Department of Organic Chemistry, State University of Ghent, Laboratory for Organic Synthesis, Krijgslaan, 281 (S. 4), B-9000, GENT, Belgium
Pages 1149-1158 | Published online: 06 Dec 2006
 
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Abstract

The synthesis of the title compound 13, via a photochemical (π2 + π2) annellation procedure and a highly stereo-selective hydrocyanation reaction, is described.

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