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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 2
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Original Articles

Synthesis of (E) and (Z) Alkenes VIA Palladium or Nickel-Catalyzed Reaction of Vinyl Chlorides with Grignard Reagents

Victoria Ratovelomanana E.R. 12 du C.N.R.S., Laboratoire de Chimie, Ecole Normale Supé rieure, 24, rue Lhomond, 75231, Paris Cedex 05, France
&
Gérard Linstrumelle E.R. 12 du C.N.R.S., Laboratoire de Chimie, Ecole Normale Supé rieure, 24, rue Lhomond, 75231, Paris Cedex 05, France
Pages 179-187 | Published online: 05 Dec 2006
 
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Abstract

We herein describe (i) a useful tranformation of (E) and (Z) vinyl chlorides into E (and Z) olefins and (ii) an efficient preparation of monoenic alcohols or acetates and an application to insect pheromones.

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