Bis[Trinitratocerium(IV)]Chromate [Ce(N0₃)₃ 1₂ Cr0₄; A Mild Oxidant in Organic Synthesis

H. Firouzabadi Department of Chemistry, Shiraz University, Shiraz, Iran

N. Iranpoor Department of Chemistry, Shiraz University, Shiraz, Iran

H. Parham Department of Chemistry, Shiraz University, Shiraz, Iran

J. Tootan Department of Chemistry, Shiraz University, Shiraz, Iran

Abstract

Bis[trinitratocerium (IV)] chromate has been prepared and used in the oxidation of benzylic alcohols to aldehydes and ketones, α-hydroxy ketones to diketones, hydroquinone to p-benzoquinone and catechol to o-benzoquinone. Cinnamyl alcohol, piperonaloxime, and salycilaldoxime are rather resistant towards oxidation with this reagent.

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Bis[Trinitratocerium(IV)]Chromate [Ce(N0₃)₃ 1₂ Cr0₄; A Mild Oxidant in Organic Synthesis

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Bis[Trinitratocerium(IV)]Chromate [Ce(N0₃)₃ 1₂ Cr0₄; A Mild Oxidant in Organic Synthesis