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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 9
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Original Articles

Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [PMO12O40]3-[C5H5N+(CH2)15CH3]3

Yasuhiro Matoba Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
,
Hiroshi Inoue Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
,
Jun-Ichi Akagi Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
,
Takuji Okabayashi Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
,
Yasutaka Ishii Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
&
Masaya Ogawa Department of applied Chemistry, Kansai University, Senriyama, Suita, Osaka, 564, Japan
Pages 865-873 | Published online: 19 Dec 2006
 
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Abstract

Applicatims a Mo- and W-based heteropoly acids (HPA) as a catalyst in the oxidation of olefins have extensively been investigated1. However, a patent work is only attempted concerning the evoxidatim of olefins with H202 by HPA2) since the oxirane ring is cleaved because of a strong acidity of HPA itself. Herein, an effective epoxidatim of some allylic alcohols with H202 by a new Mo-species (MPCP), which was prepared from 12-molybdatophosphoric acid (H3PMo12040) and cetylpyridinium chloride (C5H5N (CH2), 15CH3- C1-) under two-phase conditions using chloroform as an organic solvent, is described.

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Related Research Data

Heterogeneous catalysis by heteropoly compounds of molybdenum and tungsten
Source: Informa UK Limited
[α‐PW12O40]3− Immobilized on Ionic Liquid–Modified Polymer as a Heterogeneous Catalyst for Alcohol Oxidation with Hydrogen Peroxide
Source: Informa UK Limited
Transition-metal complexes for liquid-phase catalytic oxidation: some aspects of industrial reactions and of emerging technologies
Source: Royal Society of Chemistry (RSC)
Investigation of induction times, activity, selectivity, interface and mass transport in solvent-free epoxidation by H2O2 and TBHP: a study with organic salts of the [PMo12O40]3− anion
Source: HAL CCSD

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