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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 13
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Original Articles

Aldolic Condensations on Inorganic Solid Support: Application to the Synthesis of O-Ethyl Esters of 3-Phenyl-2-propenethioic Acids

Catherine Davrinche Laboratoire de Chimie Thérapeutique-Pharmacie Chimique Faculté de Pharmacie, rue J. B. Clément, 92290, Ch[acaron]tenay, Malabry, France
&
Jean-Daniel Brion et Pierre Reynaud Laboratoire de Chimie Thérapeutique-Pharmacie Chimique Faculté de Pharmacie, rue J. B. Clément, 92290, Ch[acaron]tenay, Malabry, France
Pages 1181-1190 | Published online: 19 Dec 2006
 
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Abstract

Aldolic condensations with 0-ethyl thioesters are performed on basic alumina to give 2,3-unsaturated thioates. The stereochemistry of the reaction is discussed and compared with Knoevenagel's, Pinner's and Wittig-Horner's reactions.

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