Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 3
48
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

Adamantyldimethylsilyl Ethers

, &
Pages 185-194 | Published online: 05 Dec 2006
 

Abstract

Adamantyldimethylsilyl ethers, prepared by reaction of the chloride with alcohols in DMF/imidazole or by [Ph3P]3RhCl catalyzed reaction of adamantyldimethylsilane with alcohols, are comparable in stability to t-butyldimethylsilyl ethers. Their hydrolysis yields the alcohol and adamantanyldimethylsilanol. Methods to convert the silanol back to the chloride or silane are given.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.