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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 3
42
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Original Articles

Electrocatalyzed Trimerization of Isocyanates to Hexahydro-s-Triazinetriones

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Pages 249-258 | Published online: 05 Dec 2006
 

Abstract

The trimerization of aryl isocyanates 2a-c to the corresponding hexahydro-s-triazinetriones 3a-c is catalyzed by anionic species obtained via the electrochemical reduction of α-bromoesters such as la, b in a potential range where isocyanates are not electroactive.

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