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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 7
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Original Articles

Synthesis of a Chiral Bicyclo[4.1.0] Allylic Nitrile Via Reductive Cyclization of a Dienyl Nitrile

T. F. Braish Department of Chemistry Purdue, University West Lafayette, IN, 47907
&
P. L. Fuchs Department of Chemistry Purdue, University West Lafayette, IN, 47907
Pages 549-567 | Published online: 05 Dec 2006
 
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Abstract

(1R, 6S)-7,7-dimethylbicyclo[4.1.0]Hept-2-ene-3-acetonitrile 8 was synthesized from (S)-(-)-Perillaldehyde in 5 steps and 65% overall yield via Mg[0] reductive cyclization.

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