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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 11
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Original Articles

An Improved Procedure for Hydrosilation of α,β-Unsaturated Esters and an Extension to Conjugated Diene Esters

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Pages 965-971 | Published online: 19 Dec 2006
 

Abstract

Treatment of α,β-unsaturated esters with triethylsilane in benzene in the presence of a catalytic amount of tris(triphenylphosphine)rhodium chloride at room temperature followed by chromatography on silica gel gave rise to the corresponding saturated esters. Under similar conditions, fully conjugated diene esters were reduced to the dihydrolevel to give β,γ- or γ,δ-unsaturated esters depending upon the substitution pattern of the starting substrate.

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