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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 12
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Original Articles

On the Synthesis and Enantiomeric Purity of (S)-4-Acetyl-2,2-Dimethyl-1,3-Dioxolane

David Tanner Department of Organic Chemistry Chalmers, University of Technology, S-412 96, Göteborg, Sweden
&
Peter Somfai Department of Organic Chemistry Chalmers, University of Technology, S-412 96, Göteborg, Sweden
Pages 1517-1522 | Published online: 06 Dec 2006
 
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Abstract

The title ketone has been synthesised in 96% e.e. from the corresponding methyl ester and MeLi. The [α]D value for the product was considerably higher than values previously reported for the enantiomer.

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