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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 12
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Original Articles

A Base-Mediated Alternative to the Orthoester Claisen Rearrangement

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Pages 1529-1534 | Published online: 06 Dec 2006
 

Abstract

The bromo-acetals (2), which may be prepared from allylic alcohols by reaction with 1,2-dibromo-1-ethoxyethane, may be converted in HMPA-Et3N to allyl 1-ethoxyvinyl ethers (1, R5 = Et) which undergo Claisen rearrangement.

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