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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 12
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Original Articles

The Reaction of Organometallic Reagents with Unsymmetrically Substituted Vinamidinium and Chloropropeniminium Salts

John T. Gupton Department of Chemistry, University of Central Florida, Orlando, Florida, 32816
,
Joe Coury Department of Chemistry, University of Central Florida, Orlando, Florida, 32816
,
Martin Moebus Department of Chemistry, University of Central Florida, Orlando, Florida, 32816
&
Susan Fitzwater Department of Chemistry, University of Central Florida, Orlando, Florida, 32816
Pages 1575-1586 | Published online: 06 Dec 2006
 
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Abstract

A variety of organometallic reagents have been found to undergo regioselective reaction with 1-aryl-vinamidinium salts and 3-aryl-3-chloropropeniminium salts. The products of such reactions were found to be α,β-unsaturated ketones and chlorovinyl amines, respectively.

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Related Research Data

Reaction of [3-(Dimethylamino)-2-Phenyl-Prop-2-en-1-Ylidene] Dimethylammonium Perchlorate with Grignard and Lithium Reagents
Source: Informa UK Limited
Aldol condensations catalyzed by Co(II) complexes of pyridine-containing copolymers.
Source: The Chemical Society of Japan
3-Chloro-2-propeniminium-salze (vinyloge Amidchloride) als vorteilhafte Synthesebausteine der organischen Chemie
Source: Georg Thieme Verlag KG
Vinyl phenyl selenide: a +CH:CH- synthon
Source: American Chemical Society (ACS)
The Reactions of an Unsubstituted Vinamidinium Salt with Organometallic Species and Reducing Agents
Source: Informa UK Limited
Borohydride and cyanoborohydride reduction of thioimonium salts. A convenient route for transformation of amides to amines
Source: American Chemical Society (ACS)

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