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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 13
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Original Articles

Palladium(O) Catalysed Isomerisation of 2,3-Epoxy Alcohols to α and β-Hydroxy Ketones

Yashwant D. Vankar Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, INDIA
,
Narayan C. Chaudhuri Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, INDIA
&
Surendra P. Singh Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, INDIA
Pages 1621-1626 | Published online: 05 Dec 2006
 
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Abstract

Isomerisation of 2,3-epoxy alcohols possessing an arylgroupat1 and/or 3 position, with Pd(PPh3)4 leads to formation of α and β-hydroxy ketones.

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