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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 6
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Original Articles

Hydro-Dehalogenation of α-Haloketones by Tin (II) Chloride and Sodium Hydrogen Sulfide

Aoi Ono Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan
,
Eiko Fujimoto Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan
&
Mika Ueno Department of Chemistry, Faculty of Education, Niigata University, Niigata, 950-21, Japan
Pages 653-657 | Published online: 06 Dec 2006
 
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Abstract

Aromatic and aliphatic α-haloketones were effectively dehalogenated by binary systems of sodium hydrogen sulfide (soft base) and a metal chloride such as tin (II) chloride, iron (II) chloride or chromium (III) chloride (hard acid).

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