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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 3
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Original Articles

Hydrqalumination of Diphenylacetylene

Mohaimed I. Al-Hassan Dept. of Chemistry, King Saud Univ., P.O. Box 2455, Riyadh-11451, Saudi Arabia
Pages 353-356 | Published online: 19 Dec 2006
 
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Abstract

It was found that diphenylacetylene reacts at 55[ddot]C with i-Bu2AlH to form cis-vinylalane. On the other hand, i-Bu2AlH adds mostly in anti-manner to diphenylacetylene at 110[ddot] C.

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