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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 2
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Original Articles

Sodium Iodide-Chlorotrimethylsilane (Or Boron Trifluo-ride Etherate) and Zinc-Chlorotrimethylsilane: Mild Reagent Systems for the Conversion of Enediones Into 1,4–Diketones

Yashwant D. Vankar Department of Chemistry, Indian Institute of Technology, Kanpur, 208016
,
G. Kumaravel Department of Chemistry, Indian Institute of Technology, Kanpur, 208016
,
Neeta Mukherjee Department of Chemistry, Indian Institute of Technology, Kanpur, 208016
&
C. Trinadha Rao Department of Chemistry, Indian Institute of Technology, Kanpur, 208016
Pages 181-187 | Published online: 05 Dec 2006
 
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Abstract

A high yielding conversion of enediones into 1,4-diketones has been found to proceed under mild conditions by using sodium iodide-chlorotrimethylsilane (or boron trifluoride etherate) and zinc-chlorotrimethyl-silane as reagent systems.

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