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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 13
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Original Articles

Asymmetric Syntheses IV: Enantioselective Synthesis of (R)-Benzylic Amines Via Alkylation of D-Camphor Ketimine

Jiang Yaozhong Institute of Organic Chemistry, Academia Sinica, Chengdu, P.R. China
,
Liu Guilan Institute of Organic Chemistry, Academia Sinica, Chengdu, P.R. China
,
Liu Jinchu Institute of Organic Chemistry, Academia Sinica, Chengdu, P.R. China
&
Zhou Changyou Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu, P.R. China
Pages 1545-1548 | Published online: 06 Dec 2006
 
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Abstract

An efficient asymmetric synthesis of (R)-benzylic amines in optical purity 36–90% had been achieved by alkylation of a chiral ketimine prepared from D-camphor and benzylamine. Diastereoselectivity in the alkylation is dependent on the alkyl halides.

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