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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 4
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Original Articles

Metallation Induced Rearrangement of Triarylphosphates to Tris (2-Hydroxyaryl) Phosphine Oxides

Balram Dhawan Petrolite Corporation, St. Louis, MO, 63119
&
Derek Redmore Petrolite Corporation, St. Louis, MO, 63119
Pages 465-468 | Published online: 05 Dec 2006
 
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Abstract

A novel one step conversion of triaryl phosphates to tris (2-hydroxyaryl) phosphine oxides involving a metallation induced triple migration of phosphorus from O°C is reported.

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