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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 3
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Original Articles

Organophosphorus Chemistry. Ester-Chloride Conversion Under Mild Conditions at Phosphorus

Lourdes Ylagan Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367
,
Anat Benjamin Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367
,
Amar Gupta Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367
&
Robert Engel Doctoral Program in Chemistry, The City University of New York, Queens College, Flushing, NY, 11367
Pages 285-289 | Published online: 05 Dec 2006
 
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Abstract

The use of triphenylphosphine dichloride as a mild reagent for the replacement of a single ester linkage by a chloride in phosphonate diesters is described. The conversion has also been accomplished using a tertiary phosphine which is polymer-bound.

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