Amberlyst 15: A Practical, Mild and Selective Catalyst for Methyl Esterification of Carboxylic Acids.¹

Marino Petrini Dipartimento di Scienze Chimiche, Università, Via S. Agostino, 1-62032, Camerino, Italy

Roberto Ballini Dipartimento di Scienze Chimiche, Università, Via S. Agostino, 1-62032, Camerino, Italy

Enrico Marcantoni Dipartimento di Scienze Chimiche, Università, Via S. Agostino, 1-62032, Camerino, Italy

Goffredo Rosini Istituto di Chimica Organica, Università, V.le Risorgimento, 4-40136, Bologna, Italy

Abstract

Mild and selective methyl esterification of carboxylic acids are realized using Amberlyst 15 as acid catalyst in methanol. No race mization, epimerization or ketalization products have been observed with this method. Excellent results are obtained in the esterifications of bile acids.

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Amberlyst 15: A Practical, Mild and Selective Catalyst for Methyl Esterification of Carboxylic Acids.¹

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Amberlyst 15: A Practical, Mild and Selective Catalyst for Methyl Esterification of Carboxylic Acids.1

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Amberlyst 15: A Practical, Mild and Selective Catalyst for Methyl Esterification of Carboxylic Acids.¹