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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 5
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Original Articles

The Reaction of Organocuprates with Bridgehead Enones

George A. Kraus Department of Chemistry, Iowa State University, Ames, IA, 50011
&
Pang Yi Department of Chemistry, Iowa State University, Ames, IA, 50011
Pages 473-480 | Published online: 06 Dec 2006
 
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Abstract

The reaction of bromoketones with organocuprates and lithium 2,6-ditert-butyl-4-methylphenoxide in ether affords good to excellent yields of ketones. The alkyl or alkenyl group is introduced via a conjugate addition to an in situ derived bridgehead enone.

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