Rate Enhancement Effects in the Dabco Catalysed Synthesis of Hydroxyalkenoate Esters

Farouk Ameer Department of Chemistry, University of Natal, Pietermaritzburg, South Africa

Siegfried E. Drewes Department of Chemistry, University of Natal, Pietermaritzburg, South Africa

Susan Freese Department of Chemistry, University of Natal, Pietermaritzburg, South Africa

Perry T. Kaye Department of Chemistry, University of Natal, Pietermaritzburg, South Africa; Department of Chemistry and Biochemistry, Rhodes University, P. O. Box 94, Grahamstown, 6140, South Africa

Abstract

Marked acceleration of the catalytic coupling of aldehydes with methyl acrylate is achieved by varying either the aldehyde or the catalytic system. Rapid and efficient formation of heterocyclic derivatives with significant synthetic potential is described.

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Rate Enhancement Effects in the Dabco Catalysed Synthesis of Hydroxyalkenoate Esters

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