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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 11
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Original Articles

The Reduction of Mannich Bases and Their Derivatives by Tri-N-Butyltin Hydride

Herbert S. I. Chao General Electric Corporate Research & Development Center, Schenectady, New York, 12301
Pages 1207-1211 | Published online: 06 Dec 2006
 
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Abstract

Overall nuclear methylation of phenols was achieved by deamination of their Mannich bases and related derivatives with tri-n-butyltin hydride. The α-methylation of ketones was also similarly achieved.

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