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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 11
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Original Articles

The Preparation of 1-Silyl, β-Allehyl Alcohols, Useful Synthetic Intermediates.

P. Bovicelli Centro di Studio per la Chimica delle Sostanze Organiche Naturali del C.H.R. c/o Dipartimento di Chimica, Universitá “La Sapienza”, P.le A. Moro. 5, 00185, ROMA
,
E. Mincione Centro di Studio per la Chimica delle Sostanze Organiche Naturali del C.H.R. c/o Dipartimento di Chimica, Universitá “La Sapienza”, P.le A. Moro. 5, 00185, ROMA
&
P. J. Parsons Department of Chemistry, the University of Southampton, Highfield, Southampton, S09 5NH, England
Pages 1231-1239 | Published online: 06 Dec 2006
 
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Abstract

The reductive rearrangement, by lithium a-luminum hydride, of 1-silyl-enyne-Ketones or esters affords the corresponding 1-siRyl-β-allenylalcohols, useful synthetic intermediates.

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