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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 4
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Original Articles

Effect of the Base on the Stereoselectivity of the Reaction of a Carbanion with an Aldehyde

Manian Ramesh U.A. 31, Laboratoire de Chimie Organique Biologique, Université Louis Pasteur, Institut de Chimie, 1 Rue Blaise Pascal, 67008, Strasbourg, France
&
Jean-François Biellmann U.A. 31, Laboratoire de Chimie Organique Biologique, Université Louis Pasteur, Institut de Chimie, 1 Rue Blaise Pascal, 67008, Strasbourg, France
Pages 333-335 | Published online: 06 Dec 2006
 
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Abstract

The reaction of the carbanion derived from phenyl isopropyl sulfoxide with benzaldehyde is very stereoselective if the carbanion is generated with butyllithium in contrast to the reaction where the carbanion is generated with lithium diisopropyl amide.

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