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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 4
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Original Articles

A Simple One-Pot Synthesis of Nitriles from Alcohols

F. Camps Departamento de Química Orgánica Biológica, C.I.D. (C.S.I.C.) Jorge Girona Salgado, 18-26, 08034, Barcelona, SPAIN
,
V. Gasol Departamento de Química Orgánica Biológica, C.I.D. (C.S.I.C.) Jorge Girona Salgado, 18-26, 08034, Barcelona, SPAIN
&
A. Guerrero Departamento de Química Orgánica Biológica, C.I.D. (C.S.I.C.) Jorge Girona Salgado, 18-26, 08034, Barcelona, SPAIN
Pages 445-452 | Published online: 06 Dec 2006
 
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Abstract

Primary alcohols are cleanly converted into nitriles in excellent yields by a new, one-pot, two-step process, involving transformation into the corresponding trifluoroacetates followed by nucleophilic substitution reaction with sodium cyanide.

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