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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 16-17
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Original Articles

Synthesis of Sulfoxides by Phase Transfer Catalyzed Oxidation of Sulfides by Cerium(IV) Ammonium Nitrate

Enrico Baciocchi Dipartinento di Chimica, Università di Rama “La Spienza”, 00185, Rama, Italy
,
Alessandro Piermattei Dipartinento di Chimica, Università di Rama “La Spienza”, 00185, Rama, Italy
&
Renzo Ruzziconi Dipartimento di Chimica, Università di Perugia, 06100, Perugia, Italy
Pages 2167-2171 | Published online: 05 Dec 2006
 
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Abstract

Diaryl, dialkyl and alkyl aryl sulfides are oxidized by cerium (IV) ammonium nitrate in H2 O/CH 2 Cl 2, in the presence of tetra-n-butylammonium bromide, at room temperature, to give sulfoxides in yields ranging between 90 and 100%.

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