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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 7
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Original Articles

Solvolysis of 1-Chloro-1-Alkenyl Phenyl Sulfides. Synthesis of α-Bromo Phenyl Thiocarboxylic Esters, α-Bromo Alkyl Carboxylic Esters and α-Phenylthio Methyl Carboxylic Esters

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Pages 751-761 | Published online: 19 Dec 2006
 

Abstract

1-chloro-1-alkenyl phenyl sulfides treated with bromine followed by hydrolysis or methanolysis give α-bromo phenyl thiocarboxylic esters and α-phenyl-thio methyl carboxylic esters. Direct oxidative solvolysis with bromine and alcohol give α-bromo alkyl carboxylic esters.

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