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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 13
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Original Articles

π4s + π2s Cycloaddition: Synthesis and OXA-DI-π-Methane Rearrangement of Annulated Bicyclo (2.2.2) Octenones

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Pages 1513-1524 | Published online: 03 Jan 2007
 

Abstract

A simple one step synthesis of tricyclo (2.2.2.02,6) tetradecadienones and 5-spiro tricyclo (2.2.2.02,6) undecadienone by trapping of 2,4-cyclohexa-dienone with various dienophiles followed by photochemical oxa-di-π-methane rearrangement of the resulting adducts to polyquinanes is described.

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