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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 13
34
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Original Articles

Novel Chloride to Bromide Exchange: Preparation of 1-Bhomoalkyl Carbonates

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Pages 1525-1530 | Published online: 03 Jan 2007
 

Abstract

A new method is described for the synthesis of 1-bromoalkyl carbonates which consists of reacting the corresponding 1-chloroalkyl carbonate with a volatile electrophilic bromine containing reagent (E-Br) and a catalyst. The equilibrium is driven to product by removal of the E-C1 formed.

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