Novel Chloride to Bromide Exchange: Preparation of 1-Bhomoalkyl Carbonates

Jean-Pierre Senet SNPE, Centre de Recherches du Bouchet, 91710, Vert-le-Petit, FRANCE

Gérard Sennyey SNPE, Centre de Recherches du Bouchet, 91710, Vert-le-Petit, FRANCE

Gary P. Wooden SNPE, Centre de Recherches du Bouchet, 91710, Vert-le-Petit, FRANCE

Abstract

A new method is described for the synthesis of 1-bromoalkyl carbonates which consists of reacting the corresponding 1-chloroalkyl carbonate with a volatile electrophilic bromine containing reagent (E-Br) and a catalyst. The equilibrium is driven to product by removal of the E-C1 formed.

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Novel Chloride to Bromide Exchange: Preparation of 1-Bhomoalkyl Carbonates

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Novel Chloride to Bromide Exchange: Preparation of 1-Bhomoalkyl Carbonates

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