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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 13
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Original Articles

An Efficient Synthesis of (±)-Cuparene from 4,4-Dimethyl-2-Cyclohexen-1-One

Min-Jen Shiao Institute of Chemistry, Academia Sinica Nankang, Taipei, Taiwan, Republic of China
,
David Liang Institute of Chemistry, Academia Sinica Nankang, Taipei, Taiwan, Republic of China
,
Chung-Shan Ku Department of Chemistry, Chung Yuan Christian University, Chungli, Taiwan, Republic of China
&
Chia-Hsi Yang Department of Chemistry, Chung Yuan Christian University, Chungli, Taiwan, Republic of China
Pages 1553-1563 | Published online: 03 Jan 2007
 
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Abstract

An efficient synthesis of (±)-cuparene 1 from 4,4-dimethyl-2-cyclohexen-1-one 2 involves 1,4-addition by use of organozinc reagent, ozonolysis and Dieckmann condensation as the key steps.

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