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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 14
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Original Articles

Easy and Efficient Heterogeneous Nucleophilic Fluorination without Solvent

Georges Bram Laboratoire des Réactions Sélectives sur Supports I.C.M.O., Université Paris Sud, B[acaron]timent 410, ORSAY Cedex, U.A. 478 du CNRS, 91405, France
,
AndrÉ Loupy Laboratoire des Réactions Sélectives sur Supports I.C.M.O., Université Paris Sud, B[acaron]timent 410, ORSAY Cedex, U.A. 478 du CNRS, 91405, France
&
Philippe Pigeon Laboratoire des Réactions Sélectives sur Supports I.C.M.O., Université Paris Sud, B[acaron]timent 410, ORSAY Cedex, U.A. 478 du CNRS, 91405, France
Pages 1661-1668 | Published online: 03 Jan 2007
 
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Abstract

In the absence of solvent, either [NBu4 F,3H2 O] or [CsF in the presence of catalytic amounts of a phase transfer catalyst] were found to be effective and practical reagents for the fluorination of several organic halides under mild conditions.

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