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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 1-2
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Original Articles

A Stereoselective Synthesis of Pear Ester Via Arsenic Ylide

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Pages 91-96 | Received 14 Jan 1988, Published online: 24 Oct 2006
 

Abstract

The paper describes a four-step synthesis of ethyl (2E, 4Z)-2, 4-decadienoate (pear ester) from propargyl alcohol with a 50% total yield. It also gives the synthesis of ethyl (2E, 4E)-2, 4-decadienoate. In both cases arsenic ylides were used to give the satisfactory results.

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