Highly Selective Synthesis of Acyclic Tert-Aliphatic Carboxylic Acids from Acyclic Tert-Alcohols Using Sulfuric Acid Supersaturated with Carbon Monoxide

Yukio Takahashi Department of Industrial Chemistry, Kitami Institute of Technology, Kitami, Japan, 090

Norihiko Yoneda Department of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo, Japan, 060

Abstract

The selective carboxylation of acyclic tert-aliphatic alcohols was successfully performed to produce the corresponding acyclic tert-aliphatic carboxylic acids in significantly high yields using concentrated sulfuric acid supersaturated with carbon monoxide.

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Highly Selective Synthesis of Acyclic Tert-Aliphatic Carboxylic Acids from Acyclic Tert-Alcohols Using Sulfuric Acid Supersaturated with Carbon Monoxide

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Highly Selective Synthesis of Acyclic Tert-Aliphatic Carboxylic Acids from Acyclic Tert-Alcohols Using Sulfuric Acid Supersaturated with Carbon Monoxide

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